The film follows the life of Napoleon from his early life in Corsica to his death at Saint Helena. The film is notable for its use of location shooting for numerous scenes, especially at the French estates of Malmaison and Fontainebleau, the Palace of Versailles, and sites of Napoleonic battles including Austerlitz and Waterloo.

Daniel Gélinas Napoléon Bonaparte
Michèle Morganas Joséphine de Beauharnais
Raymond Pellegrinas Old Napoléon Bonaparte
Sacha Guitryas Talleyrand
Jean-Pierre Aumontas Regnault de St-Jean d'Angely
Jeanne Boitelas Madame de Dino
Gilbert Bokanowskias Trader / Louis XVI (uncredited)
Pierre Brasseuras Barras
Gianna Maria Canaleas Pauline Borghese
Jean Chevrieras General Duroc